Parity Breaking in Nematic Tactoids

نویسنده

  • P Prinsen
چکیده

We theoretically investigate under what conditions the director field in a spindle-shaped nematic droplet or tactoid obtains a twisted, parity-broken structure. By minimizing the sum of the bulk elastic and surface energies, we show that a twisted director field is stable if the twist and bend elastic constants are small enough compared to the splay elastic constant, but only if the droplet volume is larger than some minimum value. We furthermore show that the transition from an untwisted to a twisted director-field structure is a sharp function of the various control parameters. We predict that suspensions of rigid, rod-like particles cannot support droplets with a parity broken structure, whereas they could possibly occur in those of semi-flexible, worm-like particles.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Chiral symmetry breaking by spatial confinement in tactoidal droplets of lyotropic chromonic liquid crystals.

In many colloidal systems, an orientationally ordered nematic (N) phase emerges from the isotropic (I) melt in the form of spindle-like birefringent tactoids. In cases studied so far, the tactoids always reveal a mirror-symmetric nonchiral structure, sometimes even when the building units are chiral. We report on chiral symmetry breaking in the nematic tactoids formed in molecularly nonchiral p...

متن کامل

Experimental realization of crossover in shape and director field of nematic tactoids.

Spindle-shaped nematic droplets (tactoids) form in solutions of rod-like molecules at the onset of the liquid crystalline phase. Their unique shape and internal structure result from the interplay of the elastic deformation of the nematic and anisotropic surface forces. The balance of these forces dictates that tactoids must display a continuous variation in aspect ratio and director-field conf...

متن کامل

Nematic droplets in aqueous dispersions of carbon nanotubes.

Aqueous dispersions of exfoliated, bile-salt stabilized single-wall carbon nanotubes exhibit a first order transition to a nematic liquid-crystalline phase. The nematic phase presents itself in the form of micron-sized nematic droplets also known as tactoids, freely floating in the isotropic host dispersion. The nematic droplets are spindle shaped and have an aspect ratio of about four, irrespe...

متن کامل

Confinement-Induced Liquid Crystalline Transitions and Chirality Inversion in Amyloid Fibril Cholesteric Tactoids

Chirality is ubiquitous in nature and plays crucial roles in biology, medicine, physics and materials science 1–5. Understanding and controlling chirality is therefore an important research challenge with broad implications in fundamental and applied sciences. Unlike other classes of chiral colloids, such as nanocellulose or filamentous viruses, amyloid fibrils form nematic phases but appear to...

متن کامل

A parity-breaking electronic nematic phase transition in the spin-orbit coupled metal Cd2Re2O7.

Strong electron interactions can drive metallic systems toward a variety of well-known symmetry-broken phases, but the instabilities of correlated metals with strong spin-orbit coupling have only recently begun to be explored. We uncovered a multipolar nematic phase of matter in the metallic pyrochlore Cd2Re2O7 using spatially resolved second-harmonic optical anisotropy measurements. Like previ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2004